Vinylidene chloride (C₂H₂Cl₂) is an important industrial chemical, but did you know it can seriously affect workers’ health? Long-term exposure can lead to respiratory and nerve damage, and an increased risk of cancer. Discover the real impacts and how to protect your health when working with this chemical!
1. What is Vinylidene chloride (Ethene, 1,1-dichloro-)?
Vinylidene chloride (Ethene, 1,1-dichloro-), with the chemical formula C₂H₂Cl₂, is an organic compound belonging to the group of halogenated hydrocarbons. It is a colorless, volatile liquid with a characteristic pungent odor. It is sparingly soluble in water but dissolves well in organic solvents such as alcohol, ether, and benzene. Due to its special chemical properties, Vinylidene chloride is widely used in industry, especially in the production of polymers, plastics, and food wrap films.
This compound has a molecular structure consisting of two carbon atoms linked by a double bond, which are also attached to two chlorine atoms. This arrangement gives it a strong ability to react with many other substances, particularly in the polymerization process to create polyvinylidene chloride (PVDC), a polymer with very high resistance to moisture vapor and gases. This makes it a crucial component in packaging materials and food preservation barrier films.
However, due to the volatile and reactive nature of Vinylidene chloride, exposure to this chemical in the work environment can pose certain risks to human health. Therefore, a clear understanding of its properties and applications is essential to ensure occupational safety in factories and production facilities that use this chemical.
| No. | Chemical Name in Vietnamese | Chemical Name in English | HS Code | CAS Number | Chemical Formula |
| 1. | Vinyliden clorua | Vinylidene chloride (Ethene, 1,1-dichloro-) | 29032900 | 75-35-4 | C2H2Cl2 |
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2. Where does Vinylidene chloride (Ethene, 1,1-dichloro-) originate from in the production process?
In industrial production processes, the compound C₂H₂Cl₂ is primarily created through the chlorination of ethylene or 1,1-dichloroethane. This reaction takes place under appropriate temperature and pressure conditions, using a catalyst to control the reaction rate and ensure the desired product yield. This is a critical stage in the production of Vinylidene chloride to supply raw materials to other industries.
In addition to synthesis, this compound can also be generated during the processing and handling of polymer plastics containing polyvinylidene chloride (PVDC). When PVDC products are heated during the production of films or the molding of plastic products, a small amount of Vinylidene chloride can be released into the environment. This commonly occurs in factories producing food packaging, synthetic fibers, and waterproof materials.
Furthermore, industrial emissions from chemical processing or the combustion of chlorine-containing products can also be a source of this compound. In some cases, Vinylidene chloride exists as a byproduct in the production of organic solvents or other halogenated chemicals. Therefore, controlling emissions and managing this compound in the production environment plays a vital role in ensuring occupational safety and limiting the impact on the surrounding environment.

3. Industries that use Vinylidene chloride (Ethene, 1,1-dichloro-) in production
In the chemical industry, the compound C₂H₂Cl₂ is primarily used in the production of polymers, especially polyvinylidene chloride (PVDC). PVDC has high resistance to moisture vapor and gases, so it is often used to produce food wrap films, food preservation packaging, and medical packaging materials. Factories that manufacture plastics and food packaging frequently use this compound in their film fabrication processes.
The textile and synthetic fiber manufacturing industry also uses C₂H₂Cl₂ to create waterproof and flame-retardant coatings for fabrics. This compound is involved in the surface treatment of fibers, helping to increase durability and resistance to environmental impacts. Companies producing insulation materials, industrial fibers, and upholstery fabrics may apply technologies related to this compound in their product processing.
Additionally, the paint, glue, and adhesive industry utilizes the properties of C₂H₂Cl₂ in the production of products with high adhesion and good chemical resistance. This compound is present in the formulation of some types of protective coatings for metal, plastic, and wood surfaces, helping to enhance corrosion and moisture resistance.
In the chemical and pharmaceutical fields, C₂H₂Cl₂ can be used as a solvent or an intermediate in the synthesis of certain special organic compounds. Some processes for producing industrial solvents, pesticides, or specialty chemicals may also generate or use this compound during raw material processing stages.
4. How does Vinylidene chloride (Ethene, 1,1-dichloro-) affect workers?
Exposure to C₂H₂Cl₂ in the work environment can cause many negative health effects, depending on the level of exposure and the duration of work in conditions containing this chemical. This compound is volatile and can enter the body through the respiratory tract, skin, or mucous membranes, causing irritation and affecting multiple organs.
When inhaling C₂H₂Cl₂ vapors for a short period, workers may experience symptoms such as headaches, dizziness, nausea, difficulty breathing, or irritation of the eyes, nose, and throat. At high concentrations, this compound can affect the central nervous system, causing loss of balance, confusion, or even unconsciousness. With long-term exposure, workers are at risk of damage to the liver, kidneys, and nervous system due to the accumulation of toxins in the body.
Besides respiratory effects, C₂H₂Cl₂ can cause skin irritation upon direct contact. Workers may suffer from dermatitis, redness, or chemical burns if appropriate protective measures are not taken. Continuous contact with this chemical without adequate protective gear significantly increases the risk of chronic diseases such as impaired liver function, neurological disorders, and cancer.
A work environment with high concentrations of C₂H₂Cl₂, especially in polymer production or plastics processing plants, can create a risk of indoor air pollution. Without effective ventilation and emission control systems, workers can be continuously exposed without realizing the level of danger.
5. Permissible safe concentration of Vinylidene chloride (Ethene, 1,1-dichloro-) for human exposure
Safe concentration limits for C₂H₂Cl₂ in the work environment are regulated by many health and environmental agencies worldwide to protect workers’ health. According to the U.S. Occupational Safety and Health Administration (OSHA), the permissible exposure limit in the workplace air is 1 ppm (parts per million) averaged over an 8-hour workday. The U.S. National Institute for Occupational Safety and Health (NIOSH) also recommends a similar limit to reduce the risk of effects on the nervous, respiratory, and hepatic systems.
In addition to the time-weighted average (TWA) exposure limit, some environmental agencies also establish a short-term exposure limit (STEL), typically at 5 ppm over a 15-minute period. Exposure to concentrations higher than this threshold for a short time can cause severe irritation to the respiratory system, eyes, and skin. In work environments where there is a risk of C₂H₂Cl₂ release, continuous monitoring systems are necessary to ensure concentrations do not exceed permissible safe levels.
In addition to international standards, each country may set its own limits based on health impact studies and specific working conditions.

At a basic level, when working in an industrial environment, adhering to safety standards and limiting exposure to Vinylidene chloride is important. Organizations like the Occupational Safety and Health Administration (OSHA) in the United States provide guidelines and safety principles to protect workers from the negative impacts of chemical substances.
6. Measures to minimize the health effects of Vinylidene chloride (Ethene, 1,1-dichloro-) on workers
Controlling the concentration of C₂H₂Cl₂ in the work environment is a crucial measure to protect workers’ health. Installing an effective ventilation system helps minimize the accumulation of chemical vapors in the air, especially in production, processing, and storage areas. Local exhaust ventilation should be used at locations with a high risk of emission to limit direct exposure to chemical vapors.
Monitoring air quality in the workplace is a necessary requirement to ensure that the concentration of C₂H₂Cl₂ does not exceed safe limits. The use of automatic measuring devices and periodic air analysis helps to promptly detect pollution, thereby enabling appropriate corrective actions. If chemical concentrations rise, it is necessary to have plans to adjust production processes or enhance personal protective measures.
Personal protective equipment plays a vital role in minimizing exposure risk. Workers in environments with C₂H₂Cl₂ should use respirators with specialized filters, chemical-resistant gloves, and appropriate protective clothing. In particular, safety goggles are necessary to protect the eyes from irritating chemical vapors. This protective equipment needs to be regularly inspected and replaced to ensure maximum protective effectiveness.
Training and raising awareness for workers about the dangers of C₂H₂Cl₂ is an important measure to limit health risks. Providing information on exposure symptoms, safe work procedures, and how to use protective equipment helps workers proactively prevent harm. In addition, companies should conduct periodic health check-ups to detect early signs of effects on the body, especially issues related to the respiratory, nervous, and hepatic systems.
Occupational safety training: Workers need to be trained and educated about the risks and safety measures when working with this type of chemical. This training should be provided periodically and regularly to ensure understanding and proper adherence to safety rules.
Periodically organize working environment monitoring in factories and enterprises, collecting and analyzing factors harmful to workers, thereby adjusting to reduce hazard levels to prevent occupational diseases for them.
7. Nationwide Working Environment Monitoring Center
Nam Viet’s working environment monitoring center is a professional unit specializing in the supervision and measurement of working environment quality across all provinces in Vietnam. With a team of experienced monitoring specialists, the center uses modern measuring equipment, ensuring accuracy and reliability.
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In addition to providing monitoring services, the center also supports clients in planning, handling, and tracking issues related to the working environment. With the motto “the customer is the center,” the center focuses on customer satisfaction, meeting all customer needs, and is committed to providing the best solutions for businesses.
With investment in techniques, technology, and human resources, Nam Viet’s monitoring center has become one of the reputable units in the field of working environment monitoring in Ho Chi Minh City with the following objectives:
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8. Quotation for working environment monitoring
To help businesses conduct working environment monitoring professionally and effectively, Nam Viet provides our customers with a quality and reasonably priced quotation for working environment monitoring services.
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